Re-Washing: How To Do It
Several formulations have been suggested by film manufacturers to promote the swelling of the emulsion, anneal the scratches and then to restabilise the emulsion to re-establish the best conditions for image permanence.
Kodak has a recommended process called RW1.
A solution of approximately 50 gms per litre of each of sodium sulphite and borax produces a rapid and even softening of almost all emulsions [a high pH is essential] and concentration and temperature is not very critical. Most laboratories use a process temperature of 20C, followed by a wash for 10 minutes at 20C and a final rinse stage of 1 minute at 20C in a 500:1 Photoflo solution to help uniform drying.
Commercial colour processing laboratories often use a process solution from the ECN2 process, the Prebath for rewashing black and white archive film, as it is already available in solution. This is a high pH sodium sulphate solution, and very effective as a rewash process. Any of these processes are good for black and white film of any period provided there is adequate washing following the softening solution. The wash must be as efficient as the usual final wash for a black and white process producing film for an archive. This aspect is covered on the chapter on Processing. A wetting agent rinse can be used after the wash.
Rewashing subtractive incorporated coupler colour films to anneal scratches is a far more complex problem. The re-wash solution can be any of those listed above although ECN2 Prebath is most commonly used, and the annealing process seems to be just as effective as with black and white with most colour films. However, in order to preserve the dyes for the future, most colour processes use a final rinse or stabiliser solution to buffer the gelatine, leave a specific internal pH, or carry out some final stabilising procedure - the dyes of most film need this to ensure optimum dye stability. The answer is to use, as a final stage, after the re-wash solution and water wash, the same process solution as was used in the original process for this film stock. Clearly, this requires identification of the film stock and knowledge of the original process. Some last solutions were pH buffers and a wetting agent, some were formaldehyde, which hardened the emulsion and restricted the breakdown of some dyes or residual couplers, and some were solutions of specialised stabiliser chemicals. One formulation used as a final rinse in the event of no information could be as follows - it is similar to that used for many colour processes between 1960 and 1990:
Formaldehyde 37% 10 ml
Wetting Agent [e.g. Photoflo] 5 ml
pH adjusted to 4.0
Water to 1L